激光-电沉积制备铝合金多级结构减反射表面

    Laser electrodeposition of hierarchical antireflection surfaces on aluminum alloy

    • 摘要: 铝合金表面的高反射率易引起严重的界面反射和杂散光效应,制约其在光电探测与航空航天领域的应用。为解决这一问题,提出一种激光-电沉积复合制备方法。采用纳秒激光在铝合金表面制备均匀微锥阵列后,电沉积MXene(Ti3C2Tx,二维过渡金属碳化物)纳米片形成微纳多级结构。结果表明,该减反射表面在可见光及近红外波段(400 nm~1 100 nm)平均反射率由42.24%降至5.7%。减反射性能的提升一方面归因于激光加工的微锥阵列增强多重反射、散射和光捕获效应,另一方面是MXene涂层带来界面耗散和光吸收效应。该方法为铝合金表面减反射功能化提供了新思路,在航空航天光电探测、光学隐身及功能表面领域具有潜在应用价值。

       

      Abstract: High reflectivity of aluminum alloy surfaces tends to cause severe interfacial reflection and stray-light effect , constraining their deployment in photoelectric detection and aerospace systems. To overcome these limitations, a hybrid laser–electrodeposition fabrication strategy was proposed. Uniform microcone arrays were constructed on aluminum alloy substrates via nanosecond laser texturing, then MXene (Ti3C2Tx, two-dimensional transition metal carbide) nanosheets were electrodeposited to form micro/nano hierarchical structures. Results showed that broadband reflectance of the antireflective surface was significantly suppressed, average reflectance decreased from 42.24% to 5.7% in visible to near-infrared wavelength range (400 nm~1100 nm. The enhanced in anti-reflection performance was attributed to two factors: on one hand, laser-fabricated micro-cone array enhanced multiple reflections, scattering, and light trapping effects; on the other hand, MXene coating introduced interfacial energy dissipation and broadband light absorption effects. This strategy provides a new route for antireflective functionalization of aluminum alloy surfaces and holds potential application value in aerospace optoelectronic detection, optical stealth, and functional surface engineering.

       

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